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Correlation between the structural disorder studied by EXAFS and the magnetic properties of intercalated MnPS3
Authors:A Michalowicz  R Clement
Institution:(1) LURE (CNRS, CEA and MEN), Université Paris-Sud, 91400 Orsay, France;(2) Laboratoire de Physicochemie Structurale, Université Paris-Val de Marne, 9400 Creteil, France;(3) Laboratoire de Physicochimie Minérale and CNRS-UA 420, Université Paris-Sud, 91405 Orsay Cedex, France
Abstract:Intercalation of various cations into layered MnPS3 induces some disorder in the local structure of Mn(II) cations, observable by EXAFS at the manganese K edge. The amplitude of this disorder effect is correlated with the amplitude of the lsquoweak ferromagnetismrsquo also observed at low temperature in the intercalates.
Keywords:Layered phosphochalcogenides  magnetic properties  EXAFS
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