Pressure dependence of the Grüneisen parameter of sodium and potassium

Temperature changes associated with adiabatic pressure changes (?T/?P)_s have been measured for sodium and potassium at room temperature (297 K) under hydrostatic pressures up to 32 kbar. For both metals a large decrease in the value of (?T/?P)_s is observed as the pressure increases. The Grüneisen parameter γ is related to (?T/?P)_s by γ = B_s(?T/?T)_s/T where B_s is the adiabatic bulk modulus. Available data for the pressure dependence of B_s and the isothermal bulk modulus B_T are used to predict the pressure and volume dependence of γ.