Thermodynamics of nitrogen-molybdenum solid solutions |
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| Authors: | R. Farraro Rex B. McLellan |
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| Affiliation: | Department of Mechanical Engineering and Materials Science, William Marsh Rice University, Houston, TX 77001, U.S.A. |
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| Abstract: | The equilibrium between N2 gas at atmospheric pressure and molybdenum-nitrogen solid solutions has been measured in the temperature range 1618–1883 K. The solvent metal was in the form of single crystals of MARZ-grade Mo. Deviations in the thermodynamic behavior consistent with a dual site occupancy mechanism, suggested by previous data, were not found.The data have been discussed in terms of the effects of hydrostatic pressure on the metal lattice and the presence of trapping sites in the solvent lattice. |
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