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A Tunable Ionic Diode Based on a Biomimetic Structure-Tailorable Nanochannel
Authors:Kai Xiao  Lu Chen  Zhen Zhang  Ganhua Xie  Pei Li  Dr Xiang-Yu Kong  Prof Liping Wen  Prof Lei Jiang
Institution:1. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P.R. China

School of Future Technologies, University of Chinese Academy of Sciences, Beijing, 101407 P.R. China;2. Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190 P.R. China;3. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P.R. China;4. Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190 P.R. China

School of Future Technologies, University of Chinese Academy of Sciences, Beijing, 101407 P.R. China

Abstract:A tunable ionic diode is presented that is based on biomimetic structure-tailorable nanochannels, with precise ion-transport characteristics from ohmic behavior to bidirectional rectification as well as gating properties. The forward/reverse directions of the ionic diode and the degree of rectification can be well-regulated by combining the patterned surface charge and the sophisticated structure. This system creates an ideal platform for precise transportation of ions and molecules, and potential applications in analytical sciences are anticipated.
Keywords:ion rectification  ion selectivity  ionic diodes  nanochannels  nanopores
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