Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles |
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| Authors: | Dr. Judit Oliver-Meseguer Prof. Antonio Doménech-Carbó Dr. Mercedes Boronat Dr. Antonio Leyva-Pérez Prof. Avelino Corma |
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| Affiliation: | 1. Instituto de Tecnología Química, Universidad Politècnica de València-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022 València, Spain;2. Departamento de Química Analítica, Universitat de València, Dr. Moliner, 50, 46100 Burjassot València), Spain |
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| Abstract: | HCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O2 and H2. The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio- and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes. |
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| Keywords: | Alkine Gold Heterogene Katalyse Hydrochlorierung Vinylchloride |
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