Template Synthesis,Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)2 Tectons Driven by Metallophilic Interactions |
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Authors: | Javier Ruiz Lucía García Daniel Sol Marilín Vivanco |
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Abstract: | A new protocol for the synthesis of protic bis(N‐heterocyclic carbene) complexes of AuI by a stepwise metal‐controlled coupling of isocyanide and propargylamine is described. They are used as tectons for the construction of supramolecular architectures through metalation and self‐assembly. Notably a unique polymeric chain of CuI with alternate AuI/bis(imidazolate) bridging scaffolds and strong unsupported CuI–CuI interactions has been generated, as well as a 28‐metal‐atoms cluster containing a nanopiece of Cu2O trapped by peripheral AuI/bis(imidazolate) moieties. |
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Keywords: | Gold Heterometallkomplexe Kupfer N-heterocyclische Carbene Selbstorganisation |
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