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A Sustainable Redox-Flow Battery with an Aluminum-Based,Deep-Eutectic-Solvent Anolyte |
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| Authors: | Dr Changkun Zhang Yu Ding Leyuan Zhang Xuelan Wang Prof Yu Zhao Prof Xiaohong Zhang Prof Guihua Yu |
| Institution: | 1. Materials Science and Engineering Program and Department of Mechanical Engineering, The University of Texas at Austin, Austin, TX, 78712 USA
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Jiangsu, 215123 China These authors contributed equally to this work.;2. Materials Science and Engineering Program and Department of Mechanical Engineering, The University of Texas at Austin, Austin, TX, 78712 USA These authors contributed equally to this work.;3. Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Jiangsu, 215123 China;4. Materials Science and Engineering Program and Department of Mechanical Engineering, The University of Texas at Austin, Austin, TX, 78712 USA |
| Abstract: | Nonaqueous redox-flow batteries are an emerging energy storage technology for grid storage systems, but the development of anolytes has lagged far behind that of catholytes due to the major limitations of the redox species, which exhibit relatively low solubility and inadequate redox potentials. Herein, an aluminum-based deep-eutectic-solvent is investigated as an anolyte for redox-flow batteries. The aluminum-based deep-eutectic solvent demonstrated a significantly enhanced concentration of circa 3.2 m in the anolyte and a relatively low redox potential of 2.2 V vs. Li+/Li. The electrochemical measurements highlight that a reversible volumetric capacity of 145 Ah L?1 and an energy density of 189 Wh L?1 or 165 Wh kg?1 have been achieved when coupled with a I3?/I? catholyte. The prototype cell has also been extended to the use of a Br2-based catholyte, exhibiting a higher cell voltage with a theoretical energy density of over 200 Wh L?1. The synergy of highly abundant, dendrite-free, multi-electron-reaction aluminum anodes and environmentally benign deep-eutectic-solvent anolytes reveals great potential towards cost-effective, sustainable redox-flow batteries. |
| Keywords: | Al batteries deep eutectic solvent energy storage halogens redox-flow batteries |