Rhodium(I)-catalyzed silylation of aryl halides with triethoxysilane: practical synthetic route to aryltriethoxysilanes |
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| Authors: | Murata Miki Ishikura Masanori Nagata Masayuki Watanabe Shinji Masuda Yuzuru |
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| Institution: | Department of Materials Science, Kitami Institute of Technology, Kitami 090-8507, Japan. muratamk@mail.kitami-u.ac.jp |
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| Abstract: | reaction: see text] The specific silylation of aryl iodides and bromides with triethoxysilane (EtO)(3)SiH in the presence of NEt(3) and a catalytic amount of Rh(cod)(MeCN)(2)]BF(4) provides the corresponding aryltriethoxysilanes in high yield. |
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