The bromopentadienyl acrylate approach to himbacine |
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Authors: | Wong Leon S-M Sharp Lisa A Xavier Natacha M C Turner Peter Sherburn Michael S |
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Institution: | School of Chemistry, University of Sydney, Sydney NSW 2006, Australia. |
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Abstract: | reaction: see text] The syntheses of 4,4a-didehydrohimbacine and 4,4a-didehydrohimandravine are presented. Key steps include an intramolecular Diels-Alder reaction of a bromopentadienyl acrylate and Suzuki-Miyaura and Stille coupling reactions. |
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