Thermodynamic study of the water—DMSO system. Part I. Features of the system: Thermodynamics,linear free-energy relationship and ortho-effects of some substituted benzoic acids in the system |
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| Authors: | F Rodante G Pistoia |
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| Institution: | Dipartimento di Ingegneria Chimica dei Materiali, delle Materie Prime e Metallurgia, Università di Roma, Via del Castro Laurenziano 7, Roma Italy;Centro di Elettrochimica e Chimica Fisica delle Interfasi del C.N.R., Via del Castro Laurenziano 7, Roma Italy |
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| Abstract: | A thermodynamic study of the water—dimethylsulfoxide (DMSO) system is presented. The features of the system are investigated by means of calorimetric and potentiometric measurements.The thermodynamics of the proton transfer process of mono-substituted benzoic acids, the linear-free energy relationship between meta and para derivatives, and ortho-effects are also presented. |
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