| Studies on the Total Synthesis of Sarcophytol-A——Synthesis of 2-Isopropyl-2-(3-Methyl-1-Benzoxyl-5-Phenylsulfonyl-3E-Pentenyl )-1,3-Dithiocyclohexane |
| |
| 基金项目： | Supported by the National Natural Science Foundation of China，State Educational Commission Foundation of China |
| |
| 摘 要： | The key intermediate, 2-isopropyl-2-(3-methyl-1-benzoxyl-5-phenylsulfonyl-3E-pentenyl)-1, 3-dithiocycllohexane(Ⅲ), for the total synthesis of Sarcophytol-A (1)was prepared through 7 steps from acetone. The key steps are nucleophilic addition of 2-1ithio-2-isopropyl-1,3-dithiocyclohexane to aldehyde 5 and double bond migration reaction of allylic alcohol 9 and 10.
|
| 收稿时间： | 1991-04-10 |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高等学校化学研究》浏览原始摘要信息 |
| 点击此处可从《高等学校化学研究》下载免费的PDF全文 |
|
