Synthesis and characterization of Zn3P2/ZnS core/shell nanowires |
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Authors: | T. SunP.C. Wu Z.D. GuoY. Dai H. MengX.L. Fang Z.J. ShiL. Dai G.G. Qin |
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Affiliation: | a State Key Laboratory for Mesoscopic Physics and School of Physics, Peking University, Beijing 100871, People?s Republic of China b Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People?s Republic of China |
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Abstract: | Fully-surrounded Zn3P2/ZnS core/shell nanowires (NWs) were synthesized for the first time via a two-step method: a catalyst free chemical vapor deposition followed by a low-pressure vulcanization process. Field emission scanning electron microscopy, high-resolution transmission electron microscopy, and high-angle angular dark field scanning transmission electron microscopy were used to characterize the morphologies, crystal structure, and element composition of the core/shell NWs. The band structure analysis demonstrates that the Zn3P2/ZnS core-shell NW type-II heterostructures have bright potential in photovoltaic nanodevice applications. The core/shell NW growth method used here can be extended to other material system. |
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Keywords: | Zn3P2 ZnS Core-shell structure Type-II |
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