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Synthesis and characterization of Zn3P2/ZnS core/shell nanowires
Authors:T. SunP.C. Wu  Z.D. GuoY. Dai  H. MengX.L. Fang  Z.J. ShiL. Dai  G.G. Qin
Affiliation:a State Key Laboratory for Mesoscopic Physics and School of Physics, Peking University, Beijing 100871, People?s Republic of China
b Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People?s Republic of China
Abstract:Fully-surrounded Zn3P2/ZnS core/shell nanowires (NWs) were synthesized for the first time via a two-step method: a catalyst free chemical vapor deposition followed by a low-pressure vulcanization process. Field emission scanning electron microscopy, high-resolution transmission electron microscopy, and high-angle angular dark field scanning transmission electron microscopy were used to characterize the morphologies, crystal structure, and element composition of the core/shell NWs. The band structure analysis demonstrates that the Zn3P2/ZnS core-shell NW type-II heterostructures have bright potential in photovoltaic nanodevice applications. The core/shell NW growth method used here can be extended to other material system.
Keywords:Zn3P2   ZnS   Core-shell structure   Type-II
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