A Three-dimensional Zinc 1,3,5-Benzenetricarboxylate with Rutile Topology Isolated in DMSO Solvothermal Reaction |
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| Authors: | YU Miao LIU Shu-Xia |
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| Institution: | 1. Department of Foundation,Jilin Business and Technology College,Changchun,Jilin 130062,China
2. Key Laboratory of Polyoxomentalate Science of Ministry of Education, College of Chemistry,Northeast Normal Uninversity, Changchun,Jilin 130024,China |
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| Abstract: | A new zinc 1,3,5-benzenetriearboxylate Zn_3(BTC)_2(DMSO)_4(BTC=1,3,5-benzenetriearboxylate)has been solvothermally synthesized in DMSO and structurally determined by X-ray single-crystal diffraction.It crystallizes in the monoclinic system,space group P2_1/c with a=10.0861(11),b=10.2527(11),c=16.4013(18)(A),β=95.478(2)°,V=1688.3(3)(A)~3,Z=2,Zn_3S_4C_(26)H_(30)O_(16),M_r=922.85,D_c=1.815 g/cm~3,F(000)=936,μ=2.434 mm~(-1),R=0.0319 and wR=0.0755.This compound consists of trimeric zinc clusters and BTC linkers.Alternate connection of these trimeric zinc clusters and BTC linkers results in a three-dimensional(3,6)-connected frame
work with rutile topology. |
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| Keywords: | coordination polymer 1 3 5-benzenetricarboxylate rutile topology DMSO solvothermal reaction |
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