Effects of textured morphology on the short circuit current of single crystalline silicon solar cells: Evaluation of alkaline wet-texture processes |
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Authors: | Soonwoo Kwon Jongheop Yi Sewang Yoon Joon Sung Lee Donghwan Kim |
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Affiliation: | aSchool of Chemical and Biological Engineering, Institute of Chemical Engineering, Seoul National University, Seoul 151-742, Republic of Korea;bR&D Center, TS Corporation, Incheon 400-201, Republic of Korea;cDepartment of Materials Science and Engineering, Korea University, Seoul 136-701, Republic of Korea |
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Abstract: | The effect of different surface morphologies obtained by anisotropic etching on the light trapping and short circuit current of single crystalline silicon solar cells was investigated. The anisotropic texturing of a (1 0 0) silicon surface was performed using potassium hydroxide (KOH) solution and/or tetramethylammonium hydroxide (TMAH) solution including isopropyl alcohol (IPA) additive or tertiary butyl alcohol (TBA) additive. Texturing in TMAH solution formed smaller pyramids on the textured surface compared with texturing in KOH solution. Although the textured samples showed similar reflectances (except in the case of the TBA additive), they showed different short circuit currents. Texturing in KOH/TMAH solution led to a 9.6% increase in short circuit current compared with texturing in KOH/IPA solution, a typical etchant in commercial processes. Based on these results, the reflectivity has no simple proportionality relationship to the short circuit current, and the short circuit current of silicon solar cells should be the criterion used in evaluating texturing effects on reducing reflectance and forming a sound junction with high collection efficiency. |
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Keywords: | Solar cell Anisotropic etch Surface texturing TMAH TBA |
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