| STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS |
| |
| 作者姓名： | 丘坤元 张景义 胡元洁 冯新德 |
| |
| 作者单位： | Department of Chemistry，Peking University，Beijing，The First Branch of Peking University，Beijing.，The First Branch of Peking University，Beijing.，Department of Chemistry，Peking University，Beijing |
| |
| 摘 要： | Radical polperization of methyl methacrylate (MMA) initiated with organic peroxide-ditertiaryamine binary systems was studied. Benzoyl peroxide (BPO), lauroyl peroxide (LPO), t-butyl hydro-peroxide (TBH), and t-butyl peroxybenzoate (TBPB) were used as organic peroxide components,aromatic ditertiay amine 4, 4′-tetramethyldiaminodiphenylmethane (TMDAPM) an d aliphatic di-tertiary amine tetramethylethylenediamine (TMEDA) were used as amine components. The polymeri-zation rate R_P, the overall activation energy of polymerization E_a, the rate equation of MMA poly-merization, and the end group of polymer formed were determined.
|
| 收稿时间： | 1984-11-09 |
STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS* |
| |
| QIU Kunyuan,ZHANG Jingyi,HU Yuanjie,FENG Xinde.STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS[J].Chinese Journal of Polymer Science,1985,0(1):76-81. |
| |
| Authors: | QIU Kunyuan ZHANG Jingyi HU Yuanjie FENG Xinde |
| |
| Institution: | Department of Chemistry; Peking University; Beijing |
| |
| Abstract: | Radical polperization of methyl methacrylate (MMA) initiated with organic peroxide-ditertiary amine binary systems was studied. Benzoyl peroxide (BPO), lauroyl peroxide (LPO), t-butyl hydro-peroxide (TBH), and t-butyl peroxybenzoate (TBPB) were used as organic peroxide components,aromatic ditertiay amine 4, 4′-tetramethyldiaminodiphenylmethane (TMDAPM) an d aliphatic di-tertiary amine tetramethylethylenediamine (TMEDA) were used as amine components. The polymeri-zation rate RP, the overall activation energy of polymerization Ea,the rate equation of MMA polymerization,and the end group of polymer formed were determined. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子科学》浏览原始摘要信息 |
| 点击此处可从《高分子科学》下载免费的PDF全文 |
|
