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Host-sensitized emission of LiInW2O8 wolframites: From red-Eu to white-Dy phosphors
Authors:S Asiri Naidu  UV Varadaraju
Institution:a Laboratoire CRISMAT (CNRS UMR6508), ENSICAEN, Université de Caen, 6 Bd. Maréchal Juin, 14050 Caen Cedex, France
b Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India
Abstract:The LiInW2O8:Eu3+, LiInW2O8:Dy3+ and LiInW2O8:Eu3+/Dy3+ phosphors were synthesized by solid-state reaction and their photoluminescence properties were studied. Under UV excitation, the LiInW2O8:Eu3+ phosphor exhibits an intense red emission whereas the LiInW2O8:Dy3+ and LiInW2O8:Dy3+/Eu3+ phosphors show a white emission. The WO6 octahedra play a major role in the luminescence of the host lattice, characterized by a blue emission under UV excitation. The emission of activator ion results from an efficient energy transfer from the LiInW2O8 host lattice to the Eu3+ and Dy3+ ions. The LiIn0.97Dy3+0.03W2O8 and LiIn0.965 Dy3+0.03Eu3+0.005W2O8 samples, optimized for white emission, are interesting candidates for solid-state lighting applications.
Keywords:LiInW2O8 wolframite  Host sensitization  Photoluminescence  Energy transfer
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