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Preparation of blue-emitting CaMgSi2O6:Eu phosphors in reverse micellar system and their application to transparent emissive display devices
Authors:Sungho Choi  Se-Won Tae  Ha-Kyun Jung
Institution:a Device Materials Research Center, Korea Research Institute of Chemical Technology, P.O. Box 107, Yuseong, Daejeon 305-600, Republic of Korea
b Seoul Semiconductor, Wonsi-dong, Danwon-gu, Ansan-city, Gyeonggi-do, Republic of Korea
c Department of Materials Science and Engineering, Korea University, Anam-dong, Seoul, Republic of Korea
Abstract:Blue-emitting Eu2+-doped CaMgSi2O6 phosphors were prepared by the reverse micelle method. The resultant particles were nanocrystalline with a grain size of about <300 nm and exhibited a characteristic blue emission spectrum centered at 445 nm induced by the oxygen coordinated Eu2+ ions. By using the corresponding nanophosphors followed by the formation of a uniform phosphor layer, we have demonstrated the mini-sized transparent plasma-discharge panels and investigated their luminance characteristics. Phosphor coated panel is properly transparent, ≥65%, at the visible wavelength region and illuminates a characteristic blue emission under Ne/Xe plasma discharge conditions. Thus, we can obtain a fast decaying, robust blue-emitting silicate phosphor layer under excited plasma radiation for upcoming emissive display devices like as transparent and three-dimensional plasma display panels.
Keywords:Nanophosphor  Luminescence  Reverse micelle  Transparent device
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