Dibromosilylene: Determination of the absolute rate constants for its gas-phase reactions with oxygen and nitric oxide |
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Authors: | V Sandhu O P Strausz T N Bell |
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Institution: | 1. Chemistry Department, University of Alberta, T6G 2G2, Edmonton, Alberta, Canada 2. Chemistry Department, Simon Fraser University, V5A 1S6, Burnaby, British Columbia, Canada
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Abstract: | Following the newly-discovered UV absorption spectrum of Br2Si, its reactions with oxygen and nitric oxide in the gas phase have been quantitatively investigated using the flash photolysis-kinetic
absorption spectroscopy technique. The room temperature bimolecular rate constants are:
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