Platinum nanoparticles on fullerene black as effective catalysts of hydrogenation |
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Authors: | S. D. Kushch N. S. Kuyunko B. P. Tarasov |
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Affiliation: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia |
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Abstract: | Fixation of platinum from H2PtCl6 on fullerene black through non-conjugate double bonds or hydroxyl groups created on their base in the presence of an organic base with postreduction by formate ions allows platinum particles of size 3–4 nm to be obtained. These compositions catalyze 1-decene and nitrobenzene hydrogenation and exceed in activity the traditional catalyst Pt/C with platinum particle size of 70–80 nm. The average size of the fixed platinum particles affects the catalytic activity stronger than the specific surface area and the electron conduction of the carrying agent. |
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