| Synthesis and Crystal Structure of the Organotin Complex [(o-Cl-PhCH_2)_3SnOCOC_(10)H_8N]·0.5C_6H_6 |
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| 引用本文： | ZHANG Fu-Xing KUANG Dai-Zhi② WANG Jian-Qiu,FENG Yong-Lan CHEN Zhi-Min.Synthesis and Crystal Structure of the Organotin Complex [(o-Cl-PhCH_2)_3SnOCOC_(10)H_8N]·0.5C_6H_6[J].结构化学,2005(3). |
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| 作者姓名： | ZHANG Fu-Xing KUANG Dai-Zhi② WANG Jian-Qiu FENG Yong-Lan CHEN Zhi-Min |
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| 作者单位： | Department of Chemistry and Material Science，Hengyang Normal University，Hengyang 421008，China |
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| 基金项目： | This work was supported by the Natural Science Foundation of Hunan Province (03JJY3005)and Key Foundation of Education Committee of Hunan Province (03A009，02C135) |
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| 摘 要： | 1 INTRODUCTION There is increasing interest in the study of orga-notin carboxylic ester compounds due to their insec-ticidal, fungicidal and antibiotic activities1, as well 2]as structure diversity. In recent years many organo-tin carboxylic ester compounds with good biologi-cal activity have been synthesized3, . Previous stu- 4]dies show that the coordination geometry of centralatom Sn …
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Synthesis and Crystal Structure of the Organotin Complex [(o-Cl-PhCH_2)_3SnOCOC_(10)H_8N]·0.5C_6H_6 |
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| Abstract: | A novel organotin complex (o-Cl-PhCH2)3SnOCOC10H8N]?0.5C6H6 has been syn- thesized, and its crystal structure was determined by X-ray diffraction. The crystal belongs to mo- noclinic, space group C2/c with a = 1.6214(5), b = 1.2033(3), c = 3.2873(10) nm, β = 91.467(5)°, V = 6.411(3) nm3, Mr = 1441.26, Z = 4, Dc = 1.493 g/cm3, μ(MoKα) = 10.79 cm-1, F(000) = 2904, R = 0.0500 and Rw = 0.0884. The bond lengths of Sn–C are 0.2150(5), 0.2157(4) and 0.2164(4) nm, and that of Sn–O is 0.2043(3) nm. The tin atom adopts a distorted tetrahedral geometry. |
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| Keywords: | organotin 3-indoleacrylic acid synthesis crystal structure |
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