首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Lewis Acid‐Induced N‐Methyleneamines as Initiators in the Synthesis of Secondary Amine‐Terminated Polymers
Authors:Jeffrey N McKnight  Eric S Tillman  Louis R Sarry
Abstract:Summary: The cationic polymerization of poly(tert‐butyl vinyl ether) using N‐methyleneamine equivalents derived from a Lewis acid/1,3,5‐trimethylhexahydro‐1,3,5‐triazine (TMTA) co‐initiating system is reported. The resulting polymers possessed secondary amine functionality at the chain terminus, verified by derivatization with 4‐chloro‐7‐nitrobenzo‐2‐oxa‐1,3‐diazole (NBD‐Cl) and subsequent analysis with GPC‐UV (470 nm) and 1H NMR.
image

Use of N‐methyleneamine equivalents lacking aryl substituents to afford amine‐terminated poly(tert‐butyl vinyl ether).

Keywords:cationic polymerization  functionalization of polymers  poly(vinyl ethers)
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号