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Authors:Upendra Nath Dash
Institution:Department of Chemistry, G.M. College, Sambalpur (Orissa) India
Abstract:Electromotive-force measurements on cells without liquid junction have been used to determine the pKa values of 7 mono-, 6 di-, and 2 tricarboxylic acids in formamide at 9 temperatures from 5 to 45°C. From the pKa values, the thermodynamic quantities ΔG0, ΔH0, and ΔS0 for the acids have been calculated in formamide at 25°C.
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