Reductive cleavage of C-OH bonds in allyl position-formation of gaseous products in the course of the cathodic reduction of some simple unsaturated alcohols |
| |
| Authors: | G Horányi G Inzelt K Torkos |
| |
| Institution: | Central Research Institute for Chemistry, Hungarian Academy of Sciences, Budapest, H-1525 Hungary;Department of Physical Chemistry and Radiology, L. Eötvös University, Budapest Hungary;Department of General and Inorganic Chemistry, L. Eötvös University, Budapest Hungary |
| |
| Abstract: | The problem of the reductive cleavage of C?OH bonds in allyl position has been considered starting from the literature data concerning the behaviour of allyl alcohol. The formation of hydrocarbons has been shown in the case of the electroreduction of crotyl alcohol, 2-butene-1,4-diol, propargyl alcohol, 2-butyne-1,4-diol and 1-butyne-3-ol. The composition of the gaseous products was analyzed, current efficiency values with respect to the hydrocarbon formation were calculated. Schemes for the reduction path were given. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
