Electrochemical behaviour of zinc(II) and nickel(II) p-diethylaminodithiobenzoate complexes a new nickel(IV) species |
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| Authors: | G Cauquis A Deronzier |
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| Institution: | 1. Laboratoire d''Electrochimie Organique et Analytique, ERA C.N.R.S. 675, 38041 Grenoble Cedex (France);2. Département de Recherche Fondamentale, Centre d''Etudes Nucléaires de Grenoble, 85X, 38041 Grenoble Cedex (France) |
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| Abstract: | The electrochemical behaviour at a platinum electrode in methylene chloride of zinc(II) and nickel(II) p-diethylaminodithiobenzoate complexes has been studied. For the zinc(II) complex the electroactive site of oxidation is the ligand and the tetrathian dication is produced. In contrast, for the nickel(II) complex the electroactive site is the metal and a stable nickel(IV) species is obtained. |
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