Self-Assembly of a Radially Functionalized Hexagonal Molecule: Hexakis(4-hydroxyphenyl)benzene |
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Authors: | Kobayashi Shirasaka Sato Horn Furukawa |
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Institution: | Department of Chemistry and Tsukuba Advanced Research Alliance Center, University of Tsukuba, Tsukuba, Ibaraki 305-8571 (Japan). |
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Abstract: | Two different porous hydrogen-bonded networks are formed by self-assembly of the radially substituted host 1. In the network of type A, formed by 1 small middle dot4 Et(2)O, all OH groups of 1 are involved in hydrogen bonding, and the molecular sheets are stacked without translation to generate extended channels that accommodate the Et(2)O molecules. Four OH groups of 1 are involved in the type B network of 1 small middle dot4 DMF, and lateral translation of the sheets in an ABAB sequence generates large chambers, each of which contains four DMF molecules. |
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