Investigation of the stereochemistry of intermolecular conjugate additions of nucleophiles to acyclic nitrosoalkenes |
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Authors: | Witek Jason A Weinreb Steven M |
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Institution: | Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA. |
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Abstract: | Michael-type conjugate additions of γ-chiral aldehyde-derived acyclic nitrosoalkenes have been explored using a series of carbon and hetero nucleophiles. In all cases examined, these reactions are stereoselective, leading exclusively to the anti products. |
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