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Investigation of the stereochemistry of intermolecular conjugate additions of nucleophiles to acyclic nitrosoalkenes
Authors:Witek Jason A  Weinreb Steven M
Institution:Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.
Abstract:Michael-type conjugate additions of γ-chiral aldehyde-derived acyclic nitrosoalkenes have been explored using a series of carbon and hetero nucleophiles. In all cases examined, these reactions are stereoselective, leading exclusively to the anti products.
Keywords:
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