Structural interconversion and regulation of optical properties of stable hypercoordinate dipyrrin-silicon complexes |
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Authors: | Sakamoto Naoya Ikeda Chusaku Yamamura Masaki Nabeshima Tatsuya |
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Affiliation: | Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. |
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Abstract: | Novel pentacoordinate dipyrrin-silicon complexes showed efficient red or near-IR fluorescence, and the structural interconversion between silanol and siloxane derivatives resulted in significant changes in the optical properties. |
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