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Structural interconversion and regulation of optical properties of stable hypercoordinate dipyrrin-silicon complexes
Authors:Sakamoto Naoya  Ikeda Chusaku  Yamamura Masaki  Nabeshima Tatsuya
Affiliation:Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
Abstract:Novel pentacoordinate dipyrrin-silicon complexes showed efficient red or near-IR fluorescence, and the structural interconversion between silanol and siloxane derivatives resulted in significant changes in the optical properties.
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