| N-甲基苯胺在不同电极材料上的循环伏安行为 |
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| 引用本文： | 高俊侠,李运输,陈琪.N-甲基苯胺在不同电极材料上的循环伏安行为[J].菏泽学院学报,2007,29(2):68-71. |
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| 作者姓名： | 高俊侠 李运输 陈琪 |
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| 作者单位： | 曲阜师范大学化学科学学院,山东曲阜273165 |
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| 基金项目： | 山东省教育厅科技计划重点项目(J04B11) |
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| 摘 要： | 以1,2-二氯乙烷为溶剂,利用循环伏安法研究了N-甲基苯胺在不同电极材料上的电子转移性质,探讨了电极反应机理.结果表明,在低浓度的非质子溶剂中,N-甲基苯胺正离子主要发生"尾-尾"耦合,其电极反应机理为包含随后转化步骤的反应过程,即ECE历程.
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| 关 键 词： | N-甲基苯胺 1 2-二氯乙烷 循环伏安 机理 |
| 文章编号： | 1673-2103（2007）02-0068-04 |
| 收稿时间： | 2007-01-31 |
| 修稿时间： | 2007-01-31 |
On Cyclic Voltammetry Behavior of N-Methylaniline at Different Electrodes |
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| GAO Jun-xia,LI Yun-shu,CHEN Qi.On Cyclic Voltammetry Behavior of N-Methylaniline at Different Electrodes[J].Journal of Heze University,2007,29(2):68-71. |
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| Authors: | GAO Jun-xia LI Yun-shu CHEN Qi |
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| Institution: | College of Chemical Science ,Quilt Normal University ,Quilt , Shandong 273165,China |
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| Abstract: | The electrochemical properties of N-Methylaniline in 1,2-dichoromethane were investigated at different elctrodes by cyclic voltammetry and discussed its mechanism.Experimental results indicated that low concentration and nonaqueous solvents were in favor of substiuated benzidine produced by tail-tail coupling of cation radicals.The electrode process was considered to be followed by ECE mechanism. |
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| Keywords: | N-methylaniline 1 2-dichoromethane cyclic voltammetry mechanism |
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