Using a Monte‐Carlo simulation of a continuous space Rod Bead Model the interface properties of systems of flexible polymer chains with different sizes of monomers are investigated. An immiscible polymer blend in the strong segregation state is modeled by a double sandwich system of chains differing by an factor of two in the size of the beads and the interfacial tension is calculated by a virial theorem method. The simulation data are compared to self‐consistent mean field and experimental data. The results show that the simulation data agree very satisfactory with mean‐field results. The interfacial tension decreases for asymmetric systems in comparison to symmetric systems with comparable volume contents of monomers and interaction strengths due to a decrease of the effective interaction. The parameters of the investigated systems are close to the properties of PS, PMMA and PI melts. A comparison with experimental results yields a very good agreement with data for PS/PMMA and less satisfactory for PS/PI. Additionally to the interfacial tension we have studied the interfacial width, the deformation of polymer chains near the interface, distributions of chain ends, monomer densities and distributions of centers of mass of chains.
Snapshot of a typical configuration for chains with different monomer sizes and equal number of monomers per chain.
