| Synthesis and Characterization of Manganese Carbonyl Compounds with PNP |
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| 作者姓名： | Shi Hua WU Qin Xing XIE Xiu Lin YANG Wei Ping HUANG Feng LU Jin Pei CHENG |
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| 作者单位： | Department of Chemistry，Nankai University，Tianjin 300071 |
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| 摘 要： | Attheendof1930s,ThesynthesisofMn(C6H6)21firstreportedbyH.Gilmanattractedmuchattention.Subsequently,manyneworgano-manganesecompoundshavebeensythesized.Inthe1950s,itwasfoundthatCPMn(CO)3andsomeofitSderivativesaughtactastheantiknockofgasolinetosubstitutetetra-ethylleadwhichisveryharmfultoourenvironment.Thisfindinghasattractedpeople'sinterestinthestudyofthisfield.Inthiswork,weobtainedtwonewcompoundsthroughthesubstitutionreactionbetweenmixeddonorphosphineligand2,6-di(hi-phenylphosphine)pyridme…
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Synthesis and Characterization of Manganese Carbonyl Compounds with PNP |
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| Shi Hua WU, Qin Xing XIE, Xiu Lin YANG,Wei Ping HUANG, Feng LU, Jin Pei CHENG.Synthesis and Characterization of Manganese Carbonyl Compounds with PNP[J].Chinese Chemical Letters,1998(10). |
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| Authors: | Shi Hua WU Qin Xing XIE Xiu Lin YANG Wei Ping HUANG Feng LU Jin Pei CHENG |
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| Abstract: | Two new carbonyl manganese compounds were obtained by reactions of 2.6-di(biphenylphosphine) pyridine (PNP) with CPMn(CO)3.The structures of the compounds were confirmed by elemental analysis, IR, 1H NMR and 31P NMR. The results showed that the mixeddonor ligand (PNP) was coordinated to manganese only through the phosphorus atom. |
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| Keywords: | carbonyl manganese mixed-donor ligand 2 6-di (bi-phenylphosphine) pyridine |
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