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A conformationally flexible tetrahydroxycalix[4]arene adopting the unusual 1,3-alternate conformation
Authors:Seri Noa  Simaan Samah  Botoshansky Mark  Kaftory Menahem  Biali Silvio E
Institution:Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.
Abstract:The use of a chiral solvating agent enabled the determination of the NMR-silent ring-inversion process of the ketocalixarene 3. Spectroscopic and crystal data indicate that 3 adopts the unusual 1,3-alternate conformation.
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