Dark and photochemical interactions of N-benzyl-1, 4-dihydronicotineamide with α, α, α′, α′-tetrabromocyclohexanone |
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Authors: | N A Yasnikova P A Kondratenko A B Uzienko V I Staninets |
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Institution: | (1) Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Ukraine;(2) Institute of Physics, Academy of Sciences of the Ukrainian SSR, Kiev |
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Abstract: | The dark and photochemical reactions of N-benzyl-1, 4-dihydronicotineamide (BDN) with , , ![agr](/content/v3nq287717245307/xxlarge945.gif) , ![agr](/content/v3nq287717245307/xxlarge945.gif) -tetrabromocyclohexanone (TBCH) in ethanolic solutions have been investigated as function of temperature and the concentration of the components in air and in the absence of oxygen. A radical-chain mechanism has been proposed that describes the reaction of BDN with TBCH.Translated from Teoreticheskaya i Eksperimental'naya Khimiya, Vol. 22, No. 3, pp. 302–309, May–June, 1986. |
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