Thermodynamic Insight into the Origin of a Calix[n]arene-[60]fullerene Interaction and its Application to a Porphyrin-[60]fullerene Energy Transfer System |
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| Authors: | Atsushi Ikeda Masaru Kawaguchi Yoshio Suzuki Tsukasa Hatano Munenori Numata Seiji Shinkai Akio Ohta Makoto Ohta |
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| Affiliation: | (1) Department of Chemistry & Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, 812-8581, Japan;(2) Department of Chemistry & Physics of Condensed Matter, Graduate School of Science, Kyushu University, Fukuoka, 812-8581, Japan |
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| Abstract: | The calixarene-fullerene interaction,which causes only a slight change in the absorptionspectra, has been substantiated by calorimetricmeasurements: the  H° values arecomparable with those obtained from the associationconstants estimated by a spectroscopic method. Furthermore, we determined the association constantbetween homooxacalix[3]arene and [60]fullerenederivatives with a porphyrin moiety by fluorescencespectra. |
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| Keywords: | calixarene [60]fullerene porphyrin inclusion complex calorimetry fluorescencespectra |
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