Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride |
| |
| Authors: | Rajendran Kamalraj V Gilheany Declan G |
| |
| Institution: | Centre for Synthesis and Chemical Biology, School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland. |
| |
| Abstract: | A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
