Preparation and reactivity of metal-containing monomers |
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| Authors: | A. B. Gavrilov T. I. Movchan A. D. Pomogailo |
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| Affiliation: | (1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | Electroreduction of methacryloylacetone and its FeIII and CuII complexes was studied by cyclic voltammetry and preparative electrolysis on a Hg electrode. The possibility of the electropolymerization of the compounds at highly negative potentials (–2.0 V, vs sce) has been demonstrated. The polymers obtained were characterized by elemental analysis, electronic, IR-, and Mössbauer spectroscopy.For part 36, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 255–261, February, 1994. |
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| Keywords: | methacryloylacetone polymethacryloylacetone methacryloylacetonates polymethacryloylacetonates electrochemical polymerization voltammetry |
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