Dimerization of the copper(II) N-methylbenzoylhydroxamic acid complex in toluene according to EPR data |
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| Authors: | A. V. Rotov E. A. Ugolkova N. N. Efimov V. V. Minin |
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| Affiliation: | 1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
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| Abstract: | The structure of copper complexes with N-methylbenzoylhydroxamic acid in toluene at 100 K has been investigated by EPR spectroscopy. In frozen solution, copper hydroxamate exists as one dimeric and two monomeric species. The relative concentrations of these species and their magnetic resonance parameters have been determined by mathematical modeling of the shape of the EPR line. |
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