| 内式及外式-5,5-二取代-3-氧代-4-氧杂三环[5,2,1,02,6]-8-癸烯类化合物的合成 |
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| 引用本文： | 汪小兰,唐士雄,蒋腊生,王长凤,曹玉蓉. 内式及外式-5,5-二取代-3-氧代-4-氧杂三环[5,2,1,02,6]-8-癸烯类化合物的合成[J]. 高等学校化学学报, 1989, 10(5): 540 |
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| 作者姓名： | 汪小兰 唐士雄 蒋腊生 王长凤 曹玉蓉 |
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| 作者单位： | 南开大学化学系 |
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| 摘 要： | 由于许多降冰片烷衍生物及内酯类化合物都是很好的香原料,可用于调制化妆品或食用香精。为了探讨结构与香气的关系,并寻找新型的香原料,我们将上述两部分骨架-降冰片烷环系及内酯环系结合在一起,合成了具有如下结构的化合物16个。
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| 关 键 词： | 5 5-二取代-3-氧代-4-氧杂三环[5 2 1 02 6]-8-癸烯 合成 IR和1H NMR谱 |
| 收稿时间： | 1987-07-07 |
Syntheses of endo or exo-5,5-Disubstituted-3-Oxo- 4-Oxatricyclo[5,2,1,02.6]8-Decenes |
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| Wang Xiaolan,Tang Shixiong,Jiang Lasheng,Wang Changfeng,Cao Yurong. Syntheses of endo or exo-5,5-Disubstituted-3-Oxo- 4-Oxatricyclo[5,2,1,02.6]8-Decenes[J]. Chemical Research In Chinese Universities, 1989, 10(5): 540 |
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| Authors: | Wang Xiaolan Tang Shixiong Jiang Lasheng Wang Changfeng Cao Yurong |
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| Affiliation: | Chemistry Department, Nankai University, Tianjin |
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| Abstract: | Eleven endo- and five e.xo-5,5-disubstituted-3-oxo-4-oxatricycIo-[5,2,1,02,6]-8-decenes were synthesized by the reaction of the corresponding cyclic anhydrides with Grignard reagents. Fourteen of these compounds are new. Their IR and 1H NMR spectra were measured. The 1H NMR spectra were discussed briefly. |
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| Keywords: | 5 5-Disubstituted-3-oxo-4-oxatricyclo C5 2 1 02'6] -8-decene Synt- hesis IR and 1HNMR spectra. |
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