Photo-and-thiol-driven trans insertion of phenylacetylene into H-Pt bonds |
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| Authors: | Ohtaka Atsushi Kuniyasu Hitoshi Kinomoto Masanori Kurosawa Hideo |
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| Institution: | Department of Molecular Chemistry and Frontier Research Center, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. |
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| Abstract: | The photo-and-thiol-driven trans insertion of phenylacetylene into H-Pt bonds of Pt(X)(H)(PPh3)2 (X = SAr, Cl, Br, and I) took place to afford Pt(Z)-C(H)=CH(Ph)](X)(PPh3)2 in good yields. |
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