Revisiting Phosphorus Analogues of Phthalimides and Naphthalimides: Syntheses and Comparative Studies |
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| Authors: | Dr Youhei Takeda Takuya Nishida Kota Hatanaka Prof?Dr Satoshi Minakata |
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| Institution: | 1. Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Yamadaoka 2‐1, Suita, Osaka 565‐0871 (Japan);2. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2‐1, Suita, Osaka 565‐0871 (Japan) |
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| Abstract: | A series of phosphorus analogues of aromatic‐fused monoimides (phthalimides and naphthalimides) bearing a mesityl group on the P center have been synthesized. In a comparison of their photophysical, electrochemical, and thermal properties with those of the corresponding imides, the impact of P incorporation was revealed. Furthermore, theoretical studies using DFT methods were conducted to understand their properties. |
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| Keywords: | electron‐deficient compounds gold phosphorus heterocycles photophysics pi interactions |
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