| 反式和顺式-1,2-二氰-(4-乙基苯)乙烯结构的谱学分析 |
| |
| 引用本文： | 陈志敏,吴谊群,左霞. 反式和顺式-1,2-二氰-(4-乙基苯)乙烯结构的谱学分析[J]. 光谱学与光谱分析, 2006, 26(11): 2046-2049 |
| |
| 作者姓名： | 陈志敏 吴谊群 左霞 |
| |
| 作者单位： | 黑龙江大学化学化工与材料学院功能材料实验室,黑龙江,哈尔滨,150080;中国科学院上海光学精密机械研究所高密度光存储实验室,上海,201800;黑龙江大学化学化工与材料学院功能材料实验室,黑龙江,哈尔滨,150080 |
| |
| 基金项目： | 国家自然科学基金 , 黑龙江省自然科学基金 |
| |
| 摘 要： | 合成了2种新型的可溶性四氮杂卟啉中间体:反式-1,2-二氰-(4-乙基苯)乙烯和顺式-1,2-二氰-(4-乙基苯)乙烯.通过UV-Vis,FTIR,GC/MS,1H NMR等方法对这2种化合物的结构进行了表征,给出了它们完整的结构信息.分析比较了顺、反异构体结构上的差异,分析两者的紫外-可见光谱(UV-Vis)、红外光谱(FTIR)和核磁共振光谱(1H NMR)谱图的差异及其产生原因.
|
| 关 键 词： | 二氰乙烯 异构体 光谱分析 |
| 文章编号： | 1000-0593（2006）11-2046-04 |
| 收稿时间： | 2005-06-28 |
| 修稿时间： | 2005-09-26 |
Spectral Analysis of the Structure of Trans/Cis-1,2-Dicyano-(p-Ethylphenyl) alkene |
| |
| CHEN Zhi-min,WU Yi-qun,ZUO Xia. Spectral Analysis of the Structure of Trans/Cis-1,2-Dicyano-(p-Ethylphenyl) alkene[J]. Spectroscopy and Spectral Analysis, 2006, 26(11): 2046-2049 |
| |
| Authors: | CHEN Zhi-min WU Yi-qun ZUO Xia |
| |
| Affiliation: | 1. Laboratory of Functional Materials, College of Chemistry and Chemical Engineering, Heilongjiang University, Harbin 150080, China;2. Laboratory of High Density Optical Storage, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy cf Sciences, Shanghai 201800, China |
| |
| Abstract: | Two precursors of soluble tetraazaporphrins,trans-1,2-dicyano-(p-ethylphenyl)alkene and cis-1,2-dicyano-(p-ethylphenyl)alkene,were synthesized.Their structures were confirmed by elemental analysis,FTIR,UV-Vis,GC/MS and()~1H NMR.The differences in isomer structures of the trans and cis-1,2-dicyano-(p-ethylphenyl)alkenes were represented by the obvious differences in the spectra of UV-Vis,FTIR and()~1H NMR.In addition,the reasons for the differences were also analyzed. |
| |
| Keywords: | 1,2-dicyanoalkene Isomer Spectral analysis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
