| PMMA型非线性光学膜的制备及其极化取向 |
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| 引用本文： | 张韬,王世伟,赵莉莎,赵冰,崔占臣.PMMA型非线性光学膜的制备及其极化取向[J].高等学校化学学报,2008,29(10):2083-2085. |
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| 作者姓名： | 张韬 王世伟 赵莉莎 赵冰 崔占臣 |
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| 作者单位： | 吉林大学超分子结构与材料教育部重点实验室,化学学院,长春,130012 |
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| 摘 要： | 采用封管反应, 以较高产率(80%以上)合成了一种PMMA型的极化非线性光学聚合物材料. 该材料具有很好的成膜性, 用电晕极化的方法使其旋涂膜中的生色团极化取向, 并利用偏振红外光谱和偏振紫外光谱等方法, 对膜中生色团极化前后的取向进行了研究.
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| 关 键 词： | 非线性光学膜 极化取向 偏振红外 偏振紫外 |
| 收稿时间： | 2008-03-17 |
Preparation and Polarizing Orientation of PMMA Types of NLO Film |
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| ZHANG Tao,WANG Shi-Wei,ZHAO Li-Sha,ZHAO Bing,CUI Zhan-Chen.Preparation and Polarizing Orientation of PMMA Types of NLO Film[J].Chemical Research In Chinese Universities,2008,29(10):2083-2085. |
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| Authors: | ZHANG Tao WANG Shi-Wei ZHAO Li-Sha ZHAO Bing CUI Zhan-Chen |
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| Institution: | Key Laboratory of Supra Molecular Structure and Materials of the Ministry of Education, College of Chemistry, Jilin University, Changchun 130012, China |
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| Abstract: | The poly(DR1A)-co-(MMA)-co-(MA)] nonlinear optical polymeric materials were prepared through sealed-tube reactive method in high yields.The material can be made into good films by spin coating,the chromophore in the films can be oriented by corona polarization.We study the chromophore oriented before and after polarization by polarized infrared spectrometry and polarized ultraviolet spectrometry. |
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| Keywords: | Nonlinear optic(NLO) film Polarization orientation Polarized infrared spectrometry Polarized ultraviolet spectrometry |
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