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| 含喹啉氧基乙酰胺型配体的锌配合物的合成、晶体结构及荧光性质 | |
| 引用本文： | 吴伟娜,王 元,唐 宁. 含喹啉氧基乙酰胺型配体的锌配合物的合成、晶体结构及荧光性质[J]. 无机化学学报, 2012, 28(2): 425-428 |
| 作者姓名： | 吴伟娜 王 元 唐 宁 |
| 作者单位： | 1. 河南理工大学物理化学学院,焦作454000;兰州大学化学化工学院和应用有机重点实验室,兰州 730000 2. 河南理工大学物理化学学院,焦作,454000 3. 兰州大学化学化工学院和应用有机重点实验室,兰州,730000 |
| 摘 要： | 合成并通过单晶衍射表征了一个配合物[ZnL(NO3)2].CH3CN(1,L=N-(1-萘基)-2-(8-喹啉氧基)乙酰胺)。在配合物1中,金属锌离子采取扭曲的四方锥的配位构型。来自配体L的1个氧原子,2个氮原子及来自2个硝酸根的2个氧原子和中心锌离子配位。配合物通过分子间的N-H…O氢键作用构筑成沿a轴的链状结构。乙腈溶液中配合物在414.8 nm处有强荧光发射。 |
| 关 键 词： | 锌配合物 晶体结构 荧光 |
Zinc Complex with Acetamide Type Ligand Bearing Quinolinyloxy Unit: Synthesis, Crystal Structure and Fluorescence Spectra |
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| WU Wei-N,WANG Yuan and TANG Ning. Zinc Complex with Acetamide Type Ligand Bearing Quinolinyloxy Unit: Synthesis, Crystal Structure and Fluorescence Spectra[J]. Chinese Journal of Inorganic Chemistry, 2012, 28(2): 425-428 | |
| Authors: | WU Wei-N WANG Yuan TANG Ning |
| Affiliation: | Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China; College of Chemistry and Chemical Engineering and State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China,Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China and College of Chemistry and Chemical Engineering and State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China |
| Abstract: | A complex,[ZnL(NO3)2]·CH3CN(1,L=N-(naphthalen-1-yl)-2-(quinolin-8-yloxy)acetamide),was synth-esized and characterized by X-ray diffraction.In complex 1,the Zn2+ center,possessing a coordination geometry closer to a distorted square-pyramidal,coordinates with one nitrogen atom from the L ligand and four oxygen atoms,two of which are from L ligand and the others are from two nitrate ligands,respectively.In the crystal,intramolecular N-H…O hydrogen bonds link the molecules into chains along the a axis.In CH3CN solution,the complex 1 exhibits strong emission band at 414.8 nm.CCDC: 848089. |
| Keywords: | zinc complex crystal structure fluorescence |
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