The folded, tetrameric phosph(III)azane macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4 |
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Authors: | Dodds Fay García Felipe Kowenicki Richard A McPartlin Mary Riera Lucía Steiner Alexander Wright Dominic S |
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Affiliation: | Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK. |
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Abstract: | The tetrameric macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4, obtained from the reaction of the phosphazane dimer [ClP(mu-NtBu)]2 with p-phenylenediamine, has an unusual folded conformation in the solid state and contains a roughly tetrahedral arrangement of endo N-H groups for the potential coordination of anions. |
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