Radical addition of methyldichlorosilane to 1-hexene and acetylene |
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| Authors: | N V Bryantseva Yu M Lugovoi and A G Shostenko |
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| Institution: | (1) Chemical Technological Institute, A-47 Moscow, USSR |
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| Abstract: | Radical interaction of methyldichlorosilane with 1-hexene (B) and acetylene (C) is shown to form addition products. The calculated Arrhenius parameters for the relative rate constant of the addition reaction amount to lg AB/AC=0.0±0.2 and EB–EC=–7.8±0.5 kJ M–1.
      ,              1- (B)  (C)      .    , : AB/AC=0,0±0,2; EB/EC=–7,8±0,5   /.
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