A vinyl substitution reaction in fluoroalkenes |
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Authors: | A. V. Fokin M. A. Landau |
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Affiliation: | (1) A. N. Nesmeyanov Institute of Elementoorganic Compounds, Academy of Sciences of the USSR, Moscow;(2) N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow |
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Abstract: | Based on the results of CNDO and INDO quantum-chemical calculations, the possibility of a vinyl substitution (along with an addition) upon reaction of perfluoropropylene, perfluoroisobutylene, and trifluorochloroethylene with alcohols, thiols, and amines, and the absence of a similar reaction in the case of tetrafluoroethylene is explained. The calculations allow the prediction that a vinyl substitution should take place in similar reactions of 1,1-di- and trifluoroethylenes, but not with mono- and 1,2-difluoroethylenes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2802–2805, December, 1991. |
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