Oxidative C-H and C-C bond cleavage by a (2,2'-bipyridine)copper(I) chloride complex |
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| Authors: | Csonka Róbert Kaizer József Giorgi Michel Réglier Marius Hajba László Mink János Speier Gábor |
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| Affiliation: | Department of Chemistry, University of Pannonia, H-8200 Veszprem, Hungary. |
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| Abstract: | Acetonitrile is easily oxygenated at ambient reaction conditions to copper(II) oxalate [Cu(bpy)(ox)] n mediated by copper(I) chloride in the presence of 3,5-di-tert-butylcatechol and 2,2'-bipyridine. In the case of other nitriles (e.g., propionitrile), instead, the unusual and selective 1,4-extradiol cleavage of 3,5-di-tert-butylcatechol occurs to give copper(II) tert-butylmaleate [Cu(bma)(bpy)(H2O)]n in good yield. |
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