Solubility of nonpolar gases in tetrahydrofuran at 0 to 30°C and 101.33 kPa partial pressure of gas |
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Authors: | F. Gibanel M. C. López F. M. Royo J. Santafé J. S. Urieta |
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Affiliation: | (1) Departmento de Química Física, Facultad de Ciencias, Ciudad Universitaria, 50009 Zaragoza, Spain |
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Abstract: | Solubility measurements of several nonpolar gases (He, Ne, Ar, Kr, Xe, H2, D2, N2, CH4, C2H4, C2H6, CF4 and SF6) in tetrahydrofuran from 0 to 30°C and 101.33 kPa partial pressure of gas are reported. Thermodynamic functions for the solution process (Gibbs energy, enthalpy, and entropies) at 25°C are evaluated from experimental values of gas solubility as mole fractions and their variation with temperature. Lennard-Jones 6–12 pair potential parameters for tetrahydrofuran are estimated using the scale particle theory; experimental solubilities as mole fraction are compared with values calculated using this theory. |
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Keywords: | Gas solubilities tetrahydrofuran nonpolar gases thermodynamic functions of solution scaled particle theory |
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