Reactions of Tin and Lead with Tricarbonylcyclopentadienylmolybdenum(II) and Tricarbonylcyclopentadienyltungsten(II) Chlorides |
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| Authors: | Piskunov A. V. Maslennikov S. V. Spirina I. V. Maslennikov V. P. Artemov A. N. |
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| Affiliation: | (1) Research Institute of Chemistry, Lobachevskii Nizhny Novgorod State University, Nizhny Novgorod, Russia |
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| Abstract: | Tin was oxidized with tricarbonylcyclopentadienylmolybdenum and tricarbonylcyclopentadienyltungsten chlorides to obtain polynuclear organometallic compounds [ 5-C5H5M(CO)3]2SnCl2 (M = Mo, W). The reactions of the above-mentioned oxidants with lead gave lead chloride and [5-C5H5M(CO)3]2 dimers. Formal-kinetic regularities of tin oxidation with tricarbonylcyclopentadienylmolybdenum chloride in N,N-dimethylformamide were found. Thermodynamic parameters of adsorption of the reagent on the metal surface were determined. |
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