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基于四硫富瓦烯衍生物Langmuir-Blodgett膜的研究进展
引用本文:李洪启,宋燕西,李秀梅.基于四硫富瓦烯衍生物Langmuir-Blodgett膜的研究进展[J].有机化学,2009,29(2):197-205.
作者姓名:李洪启  宋燕西  李秀梅
作者单位:1. 东华大学化学化工与生物工程学院,上海,201620
2. 东华大学环境科学与工程学院,上海,201620
3. 内蒙古通辽职业学院理工系,通辽,028000
基金项目:教育部留学回国人员科研启动基金,上海市自然科学基金 
摘    要:在简要介绍了Langmuir-Blodgett (LB)膜的基础上, 主要依据制备LB膜的四硫富瓦烯(TTF)衍生物化学结构的不同, 概括了基于两亲性TTF衍生物、非两亲性TTF衍生物、TTF电荷转移(CT)复合物或盐、以及TTF金属络合物LB膜的制备、结构表征与性能研究进展. 介绍了基于TTF衍生物的LB膜在导电、化学及生物传感器、光学以及磁性方面的应用, 并对基于TTF衍生物LB膜的发展进行了展望.

关 键 词:四硫富瓦烯  Langmuir-Blodgett膜  导电性  光学  传感器  磁性
收稿时间:2008-3-11
修稿时间:2008-6-25

Advances in Study on Langmuir-Blodgett Films Based on Tetrathiafulvalene Derivatives
Li Hongqi,Song Yanxi,Li Xiume.Advances in Study on Langmuir-Blodgett Films Based on Tetrathiafulvalene Derivatives[J].Chinese Journal of Organic Chemistry,2009,29(2):197-205.
Authors:Li Hongqi  Song Yanxi  Li Xiume
Institution:(a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620)
(b College of Environmental Science and Engineering, Donghua University, Shanghai 201620)
(c Department of Physics and Technology, Inner Mongolia Tongliao Vocational College, Tongliao 028000)
Abstract:After a brief introduction to Langmuir-Blodgett (LB) film, advances in preparation, structural characterization and property study of LB films based on amphiphilic tetrathiafulvalene (TTF) derivatives, non-amphiphilic TTF derivatives, TTF CT complexes or salts, and TTF metal complexes are reviewed mainly according to different structures of the TTF derivatives. Applications of LB films based on the TTF derivatives to electrical conduction, chemical sensors or biosensors, optics, and magnetism are introduced. Moreover, the development trends in research on LB films based on the TTF derivatives are proposed.
Keywords:tetrathiafulvalene  Langmuir-Blodgett film  conductivity  optics  sensor  magnetism
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