Total synthesis of the marine polypropionates,siphonarienal, siphonarienone,and pectinatone |
| |
| Authors: | Gowravaram Sabitha Peddabuddi Gopal Jhillu S Yadav |
| |
| Institution: | Organic Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| |
| Abstract: | The synthesis of the marine natural products, siphonarienal, siphonarienone, and pectinatone is described employing desymmetrization strategy to create three consecutive stereogenic centers. The key intermediate 7 was made by asymmetric hydroboration of the known meso-olefin using (?)-IPC2BH followed by PCC and Baeyer-Villiger oxidation reactions. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
